Fuel cells are really a family of technologies containing five
primary types, based on the type of "electrolyte" used. Each has specific
characteristics that may make it better for some applications than others.
- Polymer Electrolyte Fuel Cell (PEFC) or Proton Exchange Membrane
Fuel Cell (PEMFC) - The electrolyte in this type of fuel cell is an ion exchange
membrane made of some type of polymer that is a good conductor of protons.
This type of fuel cell runs at low temperatures (usually around 80-degrees
Celsius), with electrical efficiencies of about 45%, and is the primary candidate
for automotive, small stationary, and portable power applications. PEMFCs
require very pure hydrogen as the fuel.
- Phosphoric Acid Fuel Cell (PAFC) - The electrolyte in this
type of fuel cell is phosphoric acid, concentrated to 100%. PAFCs have an
operating temperature of about 100-220 degrees Celsius, and achieve an electrical
efficiency of about 37-42%. Buses and stationary applications currently use
PAFCs.
- Molten Carbonate Fuel Cell (MCFC) - The electrolyte in this
type of fuel cell is usually a combination of alkali carbonates, retained
in a ceramic matrix. The MCFC operates at 600-700 degrees Celsius. The high
temperature enables the end user to utilize both the electricity and the
thermal energy generated by the fuel cell, resulting in electrical efficiencies
of more than 70 percent. MCFCs are well-suited to large-scale stationary
applications, and are currently being demonstrated for powering buildings.
High-temperature fuel cells can more easily use a wide range of fuels without
using a "fuel reformer."
- Solid Oxide Fuel Cell (SOFC) - The electrolyte in the SOFC
is a solid, nonporous metal oxide. At temperatures over 650 degrees Celsius,
the SOFC can utilize a hydrocarbon fuel directly, without reforming, similar
to the MCFC. Also similar to the MCFC, the SOFC generates both electricity
and usable thermal energy. High-temperature SOFCs are being demonstrated
for stationary power applications, while low-temperature SOFCs are also being
looked at for automotive applications.
- Alkaline Fuel Cell (AFC) - This was one of the first modern
fuel cells to be developed, and was used to provide on-board electric power
for the Apollo space vehicle. The electrolyte in this fuel cell is Alkaline
(KOH). AFCs require pure hydrogen and pure oxygen as the reactants. The operating
temperature for this type of fuel cell is around 200 degrees Celsius.
- Other Types of Fuel Cells - There are other types of fuel cells that are relatively
newer to the family of fuel cells. The Direct Methanol Fuel Cell (DMFC) is
very similar to the PEMFC, but it is able to directly utilize liquid methanol
at the anode. There is also a Regenerative Fuel Cell, which contains a membrane
that can both electrolyze water into hydrogen and oxygen and, with the flick
of a switch, recombine the two elements, producing electricity and water. In
a Metal Air Fuel Cell, zinc pellets and an alkaline electrolyte are circulated
through the fuel cell stack and are combined with oxygen from air to create
electricity, heat and zinc oxide (in a solution of potassium zincate). The
zincate can be regenerated in a separate process into fresh zinc pellets.